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Flammable liquid warning sign

Generally, a flammable liquid means a liquid which may catch fire easily.

In the USA, there is a precise definition of flammable liquid as one with a flashpoint below 100 degrees Fahrenheit. Less-flammable liquids (with a flashpoint between 100 degrees and 200 degrees Fahrenheit) are defined as combustible liquids. This definition is used by the National Fire Protection Association, The US Department of Transportation, the US Environmental Protection Agency, the US Occupational Safety and Health Administration and others.

These categories are further subdivided, depending on the liquid's flash point and boiling point.

  • Class IA flammable liquids have a flash point below 73 °F and a boiling point below 100 °F
  • Class IB flammable liquids have a flash point below 73 °F and a boiling point greater than or equal to 100 °F
  • Class IC flammable liquids have a flash point greater than or equal to 73 °F and below 100 °F
  • Class II combustible liquids have a flash point greater than or equal to 100 °F and below 140 °F
  • Class IIIA combustible liquids have a flash point greater than or equal to 140 °F and below 200 °F
  • Class IIIB combustible liquids have a flash point greater than or equal to 200 °F

Examples of flammable liquids

Flammable liquids include, but are not limited to:

Common name CAS Number Flash point Flammability Class Autoignition Temperature
Acetone 67-64-1 -17°C IA 465°C (869°F)
Biodiesel n/a mixture >130°C (266°F) IIIB
Dimethyl ether 115-10-6 -41°C IA
Diesel n/a mixture >62°C (143°F) IIIA 210°C (410°F)
Ethanol 64-17-5 12.8°C (55°F) IA 365°C (689°F)
Ethyl ether 60-29-7 -45°C (-49°F) IA 170°C (338°F)
Gasoline n/a mixture <−40°C (−40°F) IA 246°C (475°F)
Jet fuel n/a mixture >38°C (100°F) II 210°C (410°F)
Kerosene (paraffin oil) n/a mixture >38–72°C (100–162°F) IIIA 220°C (428°F)
Methanol 67-56-1
Nitromethane 75-52-5
Vegetable oil (canola) n/a mixture IIIB 327°C (620°F)1

See also

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