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Part of a series of articles on
Nanoelectronics

Single-molecule electronics
Molecular electronics
Molecular logic gate
Molecular wires

Solid-state nanoelectronics
Nanocircuitry
Nanowires
Nanolithography
NEMS
Nanosensor

Other approaches
Nanoionics
Nanophotonics
Nanomechanics

See also
Nanotechnology

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Part of a series of articles on
Nanotechnology

History
Implications
Applications
Regulation
Organizations
In fiction and popular culture
List of topics

Subfields and related fields

Nanomaterials
Fullerenes
Carbon nanotubes
Nanoparticles

Nanomedicine
Nanotoxicology
Nanosensor

Molecular self-assembly
Self-assembled monolayer
Supramolecular assembly
DNA nanotechnology

Nanoelectronics
Molecular electronics
Nanocircuitry
Nanolithography

Scanning probe microscopy
Atomic force microscope
Scanning tunneling microscope

Molecular nanotechnology
Molecular assembler
Nanorobotics
Mechanosynthesis

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Nanoelectronics refer to the use of nanotechnology on electronic components, especially transistors. Although the term nanotechnology is generally defined as utilizing technology less than 100nm in size, nanoelectronics often refer to transistor devices that are so small that inter-atomic interactions and quantum mechanical properties need to be studied extensively. As a result, present transistors (such as CMOS90 from TSMC or Pentium 4 Processors from Intel) do not fall under this category, even though these devices are manufactured under 90nm or 65nm technology.

Nanoelectronics are sometimes considered as disruptive technology because present candidates are significantly different from traditional transistors. Some of these candidates include: hybrid molecular/semiconductor electronics, one dimensional nanotubes/nanowires, or advanced molecular electronics. The sub-voltage and deep-sub-voltage nanoelectronics are specific and important fields of R&D, and the appearance of new ICs operating almost near theoretical limit (fundamental, technological, design methodological, architectural, algorithmic) on energy consumption per 1 bit processing is inevitable. The important case of fundamental ultimate limit for logic operation is reversible computing.

Although all of these hold immense promises for the future, they are still under development and will most likely not be used for manufacturing any time soon.

Contents

Approaches to nanoelectronics

Nanofabrication

Main articles: Nanocircuitry and nanolithography

For example, single electron transistors, which involve transistor operation based on a single electron. Nanoelectromechanical systems also falls under this category.

Nanofabrication can be used to construct ultradense parallel arrays of nanowires, as an alternative to synthesizing nanowires individually.12

Nanomaterials electronics

Besides being small and allowing more transistors to be packed into a single chip, the uniform and symmetrical structure of nanotubes allows a higher electron mobility (faster electron movement in the material), a higher dielectric constant (faster frequency), and a symmetrical electron/hole characteristic.3

Also, nanoparticles can be used as quantum dots.

Molecular electronics

Main article: Molecular electronics

Single molecule devices are another possibility. These schemes would make heavy use of molecular self-assembly, designing the device components to construct a larger structure or even a complete system on their own. This can be very useful for reconfigurable computing, and may even completely replace present FPGA technology.

Molecular electronics 4 is a new technology which is still in its infancy, but also brings hope for truly atomic scale electronic systems in the future. One of the more promising applications of molecular electronics was proposed by the IBM researcher Ari Aviram and the theoretical chemist Mark Ratner in their 1974 and 1988 papers Molecules for Memory, Logic and Amplification, (see Unimolecular rectifier)56 . This is one of many possible ways in which a molecular level diode / transistor might be synthesized by organic chemistry. A model system was proposed with a spiro carbon structure giving a molecular diode about half a nanometre across which could be connected by polythiophene molecular wires. Theoretical calculations showed the design to be sound in principle and there is still hope that such a system can be made to work.

Other approaches

Nanoionics studies the transport of ions rather than electrons in nanoscale systems.

Nanophotonics studies the behavior of light on the nanoscale, and has the goal of developing devices that take advantage of this behavior.

Nanoelectronic devices

Radios

Nanoradios have been developed structured around carbon nanotubes.7

Computers

Nanoelectronics holds the promise of making computer processors more powerful than are possible with conventional semiconductor fabrication techniques. A number of approaches are currently being researched, including new forms of nanolithography, as well as the use of nanomaterials such as nanowires or small molecules in place of traditional CMOS components. Field effect transistors have been made using both semiconducting carbon nanotubes8 and with heterostructured semiconductor nanowires.9

Energy production

Research is ongoing to use nanowires and other nanostructured materials with the hope of to create cheaper and more efficient solar cells than are possible with conventional planar silicon solar cells.10 It is believed that the invention of more efficient solar energy would have a great effect on satisfying global energy needs.

There is also research into energy production for devices that would operate in vivo, called bio-nano generators. A bio-nano generator is a nanoscale electrochemical device, like a fuel cell or galvanic cell, but drawing power from blood glucose in a living body, much the same as how the body generates energy from food. To achieve the effect, an enzyme is used that is capable of stripping glucose of its electrons, freeing them for use in electrical devices. The average person's body could, theoretically, generate 100 watts of electricity (about 2000 food calories per day) using a bio-nano generator.11 However, this estimate is only true if all food was converted to electricity, and the human body needs some energy consistently, so possible power generated is likely much lower. The electricity generated by such a device could power devices embedded in the body (such as pacemakers), or sugar-fed nanorobots. A similar technology was presented in the Matrix series of science fiction major motion pictures, with robots shown enslaving mankind for its bio-energy. Much of the research done on bio-nano generators is still experimental, with Panasonic's Nanotechnology Research Laboratory among those at the forefront.

Medical diagnostics

There is great interest in constructing nanoelectronic devices121314 that could detect the concentrations of biomolecules in real time for use as medical diagnostics,15 thus falling into the category of nanomedicine.16 A parallel line of research seeks to create nanoelectronic devices which could interact with single cells for use in basic biological research.17 These devices are called nanosensors. Such miniaturization on nanoelectronics towards in vivo proteomic sensing should enable new approaches for health monitoring, surveillance, and defense technology.181920

References

  1. ^ Melosh, N.; Boukai, Akram; Diana, Frederic; Gerardot, Brian; Badolato, Antonio; Petroff, Pierre & Heath, James R. (2003). "Ultrahigh density nanowire lattices and circuits". Science 300: 112. doi:10.1126/science.1081940. 
  2. ^ Das, S.; Gates, A.J.; Abdu, H.A.; Rose, G.S.; Picconatto, C.A. & Ellenbogen, J.C. (2007). "Designs for Ultra-Tiny, Special-Purpose Nanoelectronic Circuits". IEEE Trans. on Circuits and Systems I 54: 11. doi:10.1109/TCSI.2007.907864. 
  3. ^ Goicoechea, J.; Zamarreñoa, C.R.; Matiasa, I.R. & Arregui, F.J. (2007). "Minimizing the photobleaching of self-assembled multilayers for sensor applications". Sensors and Actuators B: Chemical 126 (1): 41–47. doi:10.1016/j.snb.2006.10.037. 
  4. ^ Petty, M.C.; Bryce, M.R. & Bloor, D. (1995). An Introduction to Molecular Electronics. London: Edward Arnold. ISBN 0195211561. 
  5. ^ Aviram, A.; Ratner, M. A. (1974). "Molecular Rectifier". Chemical Physics Letters 29: 277. doi:10.1016/0009-2614(74)85031-1. 
  6. ^ Aviram, A. (1988). "Molecules for memory, logic, and amplification". Journal of the American Chemical Society 110 (17): 5687–5692. doi:10.1021/ja00225a017. 
  7. ^ Rutherglen, C. & Burke, P. (2007). "Carbon nanotube radio". Nano Lett. 7 (11): 3296–3299. doi:10.1021/nl0714839, http://pubs.acs.org/cgi-bin/sample.cgi/nalefd/2007/7/i11/html/nl0714839.html. 
  8. ^ Postma, Henk W. Ch.; Teepen, Tijs; Yao, Zhen; Grifoni, Milena & Dekker, Cees (2001). "Carbon nanotube single-electron transistors at room temperature". Science 293 (5527): 76–79. doi:10.1126/science.1061797. 
  9. ^ Xiang, Jie; Lu, Wei; Hu, Yongjie; Wu, Yue; Yan; Hao & Lieber, Charles M. (2006). "Ge/Si nanowire heterostructures as highperformance field-effect transistors". Nature 441: 489–493. doi:10.1038/nature04796. 
  10. ^ Tian, Bozhi; Zheng, Xiaolin; Kempa, Thomas J.; Fang, Ying;Yu, Nanfang; Yu, Guihua; Huang, Jinlin & Lieber, Charles M. (2007). "Coaxial silicon nanowires as solar cells and nanoelectronic power sources". Nature 449: 885–889. doi:10.1038/nature06181. 
  11. ^ "Power from blood could lead to", Sydney Morning Herald (August 4, 2003). Retrieved on 8 October 2008. 
  12. ^ LaVan, D.A.; McGuire, Terry & Langer, Robert (2003). "Small-scale systems for in vivo drug delivery". Nat Biotechnol. 21 (10): 1184–1191. doi:10.1038/nbt876. PMID 14520404. 
  13. ^ Grace, D. (2008). "Special Feature: Emerging Technologies". Medical Product Manufacturing News. 12: 22–23, http://www.mpmn-digital.com/mpmn/200803/?pg=24. 
  14. ^ Saito, S. (1997). "Carbon Nanotubes for Next-Generation Electronics Devices". Science 278: 77–78. doi:10.1126/science.278.5335.77. 
  15. ^ Cavalcanti, A.; Shirinzadeh, B.; Freitas Jr, Robert A. & Hogg, Tad (2008). "Nanorobot architecture for medical target identification". Nanotechnology 19 (1): 015103(15pp). doi:10.1088/0957-4484/19/01/015103, http://www.iop.org/EJ/abstract/0957-4484/19/1/015103. 
  16. ^ Cheng, Mark Ming-Cheng; Cuda, Giovanni; Bunimovich, Yuri L; Gaspari, Marco; Heath, James R; Hill, Haley D; Mirkin,Chad A; Nijdam, A Jasper; Terracciano, Rosa; Thundat, Thomas & Ferrari, Mauro (2006). "Nanotechnologies for biomolecular detection and medical diagnostics". Current Opinion in Chemical Biology 10: 11–19. doi:10.1016/j.cbpa.2006.01.006. 
  17. ^ Patolsky, F.; Timko, B.P.; Yu, G.; Fang, Y.; Greytak, A.B.; Zheng, G. & Lieber, C.M. (2006). "Detection, stimulation, and inhibition of neuronal signals with high-density nanowire transistor arrays". Science 313: 1100–1104. doi:10.1126/science.1128640. 
  18. ^ Frist, W.H. (2005). "Health care in the 21st century". N. Engl. J. Med. 352 (3): 267–272. doi:10.1056/NEJMsa045011, http://content.nejm.org/cgi/content/full/352/3/267. 
  19. ^ Cavalcanti, A.; Shirinzadeh, B.; Zhang, M. & Kretly, L.C. (2008). "Nanorobot Hardware Architecture for Medical Defense". Sensors 8 (5): 2932–2958. doi:10.3390/s8052932, http://www.mdpi.org/sensors/papers/s8052932.pdf. 
  20. ^ Couvreur, P. & Vauthier, C. (2006). "Nanotechnology: intelligent design to treat complex disease". Pharm. Res. 23 (7): 1417–1450. doi:10.1007/s11095-006-0284-8. PMID 16779701. 

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